Hi Monika,
at the current point in time, the majority of the tiles in the roles above in on-premise installations will not be newly developed Fiori tiles but links to Web GUI transactions that open up in a browser pop-up window, i.e. as Mark observed below, they will also not be mentioned in the Fiori library). I hope that clarifies the confusion.
Wrt. to the blank window issue:
The Web GUI URLs will point to something like
vhcals4hci.dummy.nodomain:44300/sap/bc/ui5_ui5/ui2/ushell/shells/abap/FioriLaunchpad.html?sap-client=100&sap-language=EN&sap-sec_session_created=X#SalesQuotation-create
Any log in the browser console when you run this ? Pop-up blocker or other browser plugins ? Errors/deactivated services in TA SICF ?
Best,
Joerg